TY - JOUR ID - 63202 TI - Magnetically recyclable nanocatalysts based on magnetite: an environmentally friendly and recyclable catalyst for esterification reactions JO - Biofuel Research Journal JA - BRJ LA - en SN - AU - dos Santos-Durndell, Vannia Cristina AU - Machado Peruzzolo, Tailor AU - Ucoski, Geani Maria AU - Ramos, Luiz Pereira AU - Nakagaki, Shirley AD - Laboratório de Química Bioinorgânica e Catálise, Universidade Federal do Paraná (UFPR), Departamento de Química, Centro Politécnico, CP 19072, CEP 81531-980, Curitiba, Paraná, Brazil. Y1 - 2018 PY - 2018 VL - 5 IS - 2 SP - 806 EP - 812 KW - Magnetite KW - Silica KW - Esterification KW - Fatty acid methyl esters KW - Biodiesel DO - 10.18331/BRJ2018.5.2.4 N2 - Solid magnetic nanoparticles (magnetite = Mag) composed of Fe3O4 and magnetite coated with silica (Fe3O4/SiO2 = Mag/Si) were prepared from inexpensive starting materials. The catalytic activity of the solids was investigated for palmitic acid esterification with methanol under solvothermal conditions. Both pure Fe3O4 (Mag) and silica-coated (Mag/Si) nanoparticles exhibited high catalytic activities and were easy to recover from the reaction environment using an external magnet. Furthermore, the magnetic nanoparticle catalysts were reused without significant loss of catalytic activity and showed high durability in typical acid-catalyzed reactions. XRD and SEM analyses were conducted before and after esterification, showing almost identical particle distribution in both fresh and reused catalysts. UR - https://www.biofueljournal.com/article_63202.html L1 - https://www.biofueljournal.com/article_63202_f9b815fa0c9e5cd171914e960653cfaa.pdf ER -