A review on the effects of ethanol/gasoline fuel blends on NOX emissions in spark-ignition engines

Document Type : Review Paper

Authors

Dipartimento di Ingegneria Industriale, Università degli Studi di Napoli Federico II, Via Claudio 21, 80125 Napoli, Italy.

Abstract

Ethanol can be used as an alternative fuel for spark-ignition (SI) engines to increase the octane number and oxygen content of ethanol/gasoline blends, thereby reducing dependence on fossil fuels and the exhaust emissions of incomplete combustion products. Although it is widely agreed that ethanol can reduce CO and HC exhaust emissions, the literature on ethanol and NOX emissions is far from conclusive; hence there is a need for an in-depth, updated review of ethanol/gasoline blends in SI engines and the relative production of NOX emissions. In light of that, the present work aims to provide a comprehensive literature review on the current state of ethanol combustion in SI engines to shed definitive light on the potential changes in NOX emissions under various operating conditions. The first part of this paper discusses the feasibility of ethanol as an alternative transportation fuel, including world production and ethanol production processes. The physicochemical properties of ethanol and gasoline are then compared to analyze their effects on combustion efficiency and exhaust emissions. Then, the pathways of NOX formation inside the cylinder of SI engines are discussed in depth. Finally, we review and critically discuss the effects of ethanol concentration in blends and different engine parameters on NOX formation.

Graphical Abstract

A review on the effects of ethanol/gasoline fuel blends on NOX emissions in spark-ignition engines

Highlights

  • Physicochemical properties of ethanol and gasoline are compared.
  • NOX formation pathways are reviewed and explained.
  • Effects of ethanol/gasoline blends on NOX formation in SI engines are reviewed and discussed.
  • NOX emissions are largely dependent on ethanol concentration and engine operating conditions.

Keywords


  1. Al-Baghdadi, M.A.R.S., 2008. Measurement and prediction study of the effect of ethanol blending on the performance and pollutants emission of a four-stroke spark ignition engine. Proc. Inst. Mech. Eng., Part D: J. Automob. Eng. 222(5), 859-873.
  2. Al-Farayedhi, A., Al-Dawood, A., Gandhidasan, P., 2000. Effects of blending crude ethanol with unleaded gasoline on exhaust emissions of SI engine. SAE Technical Paper. 2000-01-2857.
  3. Amirante, R., Distaso, E., Di Iorio, S., Sementa, P., Tamburrano, P., Vaglieco, B.M., Reitz, R.D., 2017. Effects of natural gas composition on performance and regulated, greenhouse gas and particulate emissions in spark-ignition engines. Energy Convers. Manage. 143, 338-347.
  4. Awad, O.I., Ali, O.M., Mamat, R., Abdullah, A., Najafi, G., Kamarulzaman, M.K., Yusri, I.M., Noor, M.M., 2017. Using fusel oil as a blend in gasoline to improve SI engine efficiencies: a comprehensive review. Renew. Sust. Energy Rev. 69, 1232-1242.
  5. Awad, O.I., Mamat, R., Alib, O.M., Sidik, N.A.C., Yusaf, T., Kadirgama, K., Kettnere, M., 2018a. Alcohol and ether as alternative fuels in spark ignition engine: a review. Renew. Sustain. Energy Rev. 82, 2586-2605.
  6. Awad, O.I., Mamat, R., Ibrahim, T.K., Hammid, A.T., Yusri, I.M., Hamidi, M.A., Humada, A.M., Yusop, A.F., 2018b. Overview of the oxygenated fuels in spark ignition engine: environmental and performance. Renew. Sust. Energy Rev. 91, 394-408.
  7. Bae, C., Kim, J., 2017. Alternative fuels for internal combustion engines. Proc. Combust. Inst. 36(3), 3389-3413.
  8. Balki, M.K., Sayin, C., Canakci, M., 2014. The effect of different alcohol fuels on the performance, emission and combustion characteristics of a gasoline engine. Fuel. 115, 901-906.
  9. Bayraktar, H., 2005. Experimental and theoretical investigation of using gasoline-ethanol blends in spark-ignition engines. Renewable Energy. 30(11), 1733-1747.
  10. Benajes, J., García, A.,  Monsalve-Serrano, J.,  Sari, R.L., 2018. Fuel consumption and engine-out emissions estimations of a light-duty engine running in dual-mode RCCI/CDC with different fuels and driving cycles. Energy. 157, 19-30.
  11. Bharath, B.K., Selvan, V.A.M., 2021. Influence of higher alcohol additives in methanol-gasoline blends on the performance and emissions of an unmodified automotive si engine: a review. Arabian J. Sci. Eng. 1-29.
  12. Bhasker, J.P., Porpatham, E., 2017. Effects of compression ratio and hydrogen addition on lean combustion characteristics and emission formation in a compressed natural gas fuelled spark ignition engine. Fuel. 208, 260-270.
  13. Bielaczyc, P., Szczotka, A., Woodburn, J., 2011. The effect of various petrol-ethanol blends on exhaust emissions and fuel consumption of an unmodified light-duty SI vehicle. SAE Tech. Paper. 2011-24-0177.
  14. Biswal, A., Gedam, S., Balusamy, S., Kolhe, P., 2020. Effects of using ternary gasoline-ethanol-LPO blend on PFI engine performance and emissions. Fuel. 281, 118664.
  15. Boulahlib, M.S., Medaerts, F., Boukhalfa, M.A., 2018. Experimental study of combustion performances and emissions of a spark ignition cogeneration engine operating in lean conditions using different fuels. Int. J. Hydrogen Energy. 43(6), 3586-3596.
  16. Broustail, G., Halter, F., Seers, P., Moréac, G., Mounaim-Rousselle, C., 2012. Comparison of regulated and non-regulated pollutants with iso-octane/butanol and iso-octane/ethanol blends in a port-fuel injection Spark-Ignition engine. Fuel. 94, 251-261.
  17. Canakci, M., Ozsezen, A.N., Alptekin, E., Eyidogan, M., 2013. Impact of alcohol-gasoline fuel blends on the exhaust emission of an SI engine. Renewable Energy. 52, 111-117.
  18. Carneiro, M.L.N., Pradelle, F., Braga, S.L.,. Gomes, M.S.P,. Martins, A.R.F, Turkovics, , Turkovics, F., Pradelle, R.N., 2017. Potential of biofuels from algae: comparison with fossil fuels, ethanol and biodiesel in Europe and Brazil through life cycle assessment (LCA). Renew. Sust. Energy Rev. 73, 632-653.
  19. Celik, M.B., 2008. Experimental determination of suitable ethanol-gasoline blend rate at high compression ratio for gasoline engine. Appl. Therm. Eng. 28(5-6), 396-404.
  20. Chansauria, P., Mandloi, R.K., 2018. Effects of ethanol blends on performance of spark ignition engine-a review. Mater. Today Proc. 5(2), 4066-4077.
  21. Chen, R.H., Chiang, L.B., Chen, C.N., Lin, T.H., 2011. Cold-start emissions of an SI engine using ethanol-gasoline blended fuel. Appl. Therm. Eng. 31(8-9), 1463-1467.
  22. Chen, Y.L., Chen, S., Tsai, C.Y., Sun, R.H., Tsai, J.M., Liu, S.Y., 2010. Effects of ethanol-gasoline blends on engine performance and exhaust emissions in motorcycle. Proceedings of the 5th international symposium on machinery and mechatronics for agriculture and biosystems engineering. Fukuoka, Japan.
  23. Chong, J.J., Tsolakis, A., Gill, S.S., Theinnoi, K., Golunski, S.E., 2010. Enhancing the NO2/NOx ratio in compression ignition engines by hydrogen and reformate combustion, for improved after treatment performance. Int. J. Hydrogen Energy. 35(16), 8723-8732.
  24. Costa, R.C., Sodré, J.R., 2010. Hydrous ethanol vs. gasoline-ethanol blend: engine performance and emissions. Fuel. 89(2), 287-293.
  25. Costagliola, M.A., Prati, M.V., Florio, S., Scorletti, P., Iodice, P., Buono, D., Senatore, A., 2016. Performances and emissions of a 4-stroke motorcycle fuelled with ethanol/gasoline blends. Fuel. 183, 470-477.
  26. Deng, X., Chen, Z., Wang, X., Zhen, H., Xie, R., 2018. Exhaust noise, performance and emission characteristics of spark ignition engine fuelled with pure gasoline and hydrous ethanol gasoline blends. Case Stud. Therm. Eng. 12, 55-63.
  27. Dhande, D.Y., Sinaga, N.,. Dahe, K.B., 2021. The study of performance and emission characteristics of a spark ignition (SI) engine fueled with diferent blends of pomegranate ethanol. Int. J. Energy Environ. Eng. 12(2), 295-306.
  28. Dernotte, J., Mounaim-Rousselle, C., Halter, F., Seers, P., 2010. Evaluation of butanol-gasoline blends in a port fuel-injection, spark-ignition engine. Oil Gas Sci. Technol. Revue de l’Institut Français du Pétrole. 65(2), 345-351.
  29. Dogan, B., Erol, D., Yaman, H., Kodanli, E., 2017. The effect of ethanol-gasoline blends on performance and exhaust emissions of a spark ignition engine through exergy analysis. Appl. Therm. Eng. 120, 433-443.
  30. Elfasakhany, A., 2016. Experimental study of dual n-butanol and iso-butanol additives on spark-ignition engine performance and emissions. Fuel. 163, 166-174.
  31. Erdiwansyah, Mamat, R., Sani,S.M., Sudhakar, K., Asep Kadarohman, Sardjono, R.E., 2019. An overview of higher alcohol and biodiesel as alternative fuels in engines. Energy Rep. 5, 467-479.
  32. Fajri, R., Jafari, M.J., Shamekhi, A.H., Jazayeri, S.A., 2017. A numerical investigation of the effects of combustion parameters on the performance of a compression ignition engine toward NOX emission reduction. J. Clean. Prod. 167, 140-153.
  33. Flavin, C., Sawin, J.L., Mastny, L., Aeck, M., Hunt, S., MacEvitt, A,, Stair, P., Podesta, J., Cohen, A.U., Hendricks, B., 2006. American energy: the renewable path to energy security. Worldwatch Institute and the Center for American Progress, Washington, DC.
  34. Gautam, M., Martin, D.W., Carder, D., 2000. Emissions characteristics of higher alcohol/gasoline blends. Proc. Inst. Mech. Eng., Part A: J. Power Energy. 214(2), 165-182.
  35. Genchi, G., Pipitone, E., 2014. Octane rating of natural gas-gasoline mixtures on CFR engine. SAE Int. J. Fuels Lubricants. 7(3), 1041-1049.
  36. Geng, P., Cao, E., Tan, Q., Wei, L., 2017. Effects of alternative fuels on the combustion characteristics and emission products from diesel engines: a review. Renew. Sust. Energy Rev. 71, 523-534
  37. Gomes, P., Ecker, R., Kulzer, A., Kufferath, A., Conti, E., 2011. Study on boosted direct injection si combustion with ethanol blends and the influence on the ignition system. SAE Technical Paper. 2011-36-0196.
  38. Gonca, G., 2017. Influences of different fuel kinds and engine design parameters on the performance characteristics and NO formation of a spark ignition (SI) engine. Appl. Therm. Eng. 127, 194-202.
  39. Gravalos, I., Moshou, D., Gialamas, T., Xyradakis, P., Kateris, D., Tsiropoulos, Z., 2011. Performance and Emission Characteristics of Spark Ignition Engine Fuelled with Ethanol and Methanol Gasoline Blended Fuels. Altern. Fuel. 85.
  40. Guo, T., Duan, X., Liu, Y., Liu, J., Zhou, X., Li, Y., Lai, M.C., Guo, G., 2020. A comparative experimental study on emission characteristics of a turbocharged gasoline direct-injection (TGDI) engine fuelled with gasoline/ethanol blends under transient cold-start and steady-state conditions. Fuel. 277, 118153.
  41. Hahn-Hagerdal, B., Galbe, M., Gorwa-Grauslund, M.F., Liden, G., Zacchi, G., 2006. Bio-ethanol-the fuel of tomorrow from the residues of today. Trends Biotechnol. 24(12), 549-556.
  42. Hassan, N.M.S., Rasul, M.G., Harch, C.A., 2015. Modelling and experimental investigation of engine performance and emissions fuelled with biodiesel produced from Australian Beauty Leaf Tree. Fuel. 150, 625-635.
  43. He, B.Q., Wang, J.X., Hao, J.M., Yan, X.G., Xiao, J.H., 2003. A study on emission characteristics of an EFI engine with ethanol blended gasoline fuels. Atmos. Environ. 37(7), 949-957.
  44. Hosseini, S.E., Wahid, M.A., 2013. Feasibility study of biogas production and utilization as a source of renewable energy in Malaysia. Renew. Sust. Energy Rev. 19, 454-462.
  45. Hsieh, W.D., Chen, R.H., Wu, T.L., Lin, T.H., 2002. Engine performance and pollutant emission of an SI engine using ethanol–gasoline blended fuels. Environ. 36(3), 403-410.
  46. Iliev, S.A., 2021. Comparison of ethanol, methanol, and butanol blending with gasoline and its effect on engine performance and emissions using engine simulation. Processes. 9(8), 1322.
  47. Iodice, P., Cardone, M., 2021. Ethanol/gasoline blends as alternative fuel in last generation spark-ignition engines: a review on CO and HC engine out emissions. Energies. 14(13), 4034.
  48. Iodice, P., Senatore, A., 2016. New research assessing the effect of engine operating conditions on regulated emissions of a 4-stroke motorcycle by test bench measurements. Environ. Impact Assess. Rev. 61, 61-67.
  49. Iodice, P., Senatore, A., Langella, G., Amoresano, A., Advantages of ethanol-gasoline blends as fuel substitute for last generation SI engines. Environ. Prog. Sustainable Energy. 36(4), 1173-1179.
  50. Iodice, P., Langella, G., Amoresano, A., 2018. Ethanol in gasoline fuel blends: effect on fuel consumption and engine out emissions of SI engines in cold operating conditions. Appl. Therm. Eng. 130(5), 1081-1089.
  51. Jamrozik, A., Tutak, W., Pyrc, M., Gruca, M., Kočiško, M. 2018. Study on co-combustion of diesel fuel with oxygenated alcohols in a compression ignition dual-fuel engine. Fuel. 221, 329-345.
  52. Jamuwa, D.K., Sharma, D., Soni, S.L., 2016. Experimental investigation of performance, exhaust emission and combustion parameters of stationary compression ignition engine using ethanol fumigation in dual fuel mode. Energy Convers. Manage. 115, 221-231.
  53. Jia, L.W., Shen, M.Q., Wang, J., Lin, M.Q., 2005. Influence of ethanol-gasoline blended fuel on emission characteristics from a four-stroke motorcycle engine. J. Hazard. Mater.123(1-3), 29-34.
  54. Keskin, A., Gürü, M., 2011. The effects of ethanol and propanol additions into unleaded gasoline on exhaust and noise emissions of a spark ignition engine. Energy Sources, PartA. 33(23), 2194-2205.
  55. Khan, M.I., 2017. Policy options for the sustainable development of natural gas as transportation fuel. Energy Policy. 110, 126-136.
  56. Koç, M., Sekmen, Y., Topgül, T., Yücesu, H.S., 2009. The effects of ethanol-unleaded gasoline blends on engine performance and exhaust emissions in a spark-ignition engine. Renewable Energy. 34(10), 2101-2106.
  57. Kul, B.S., Ciniviz, M., 2021. An evaluation based on energy and exergy analyses in SI engine fueled with waste bread bioethanol-gasoline blends. Fuel. 286, 119375.
  58. Kumar, B.R., Saravanan, S., 2016. Use of higher alcohol biofuels in diesel engines: a review. Renew. Sust. Energy Rev. 60, 84-115.
  59. Laurini, M.P., 2017. The spatio-temporal dynamics of ethanol/gasoline price ratio in Brazil. Renew. Sust. Energy Rev. 70, 1-12.
  60. Li, Y., Chen, Y., Wu, G., Lee, C.F., Liu, J., 2018. Experimental comparison of acetone-n-butanol-ethanol (ABE) and isopropanol-n-butanol-ethanol (IBE) as fuel candidate in spark-ignition engine. Appl. Therm. Eng. 133, 179-187.
  61. Li, Y., Gong, J., Deng, Y., Yuan, W., Fu, J., Zhang, , 2017. Experimental comparative study on combustion, performance and emissions characteristics of methanol, ethanol and butanol in a spark ignition engine. Appl. Therm. Eng. 115, 53-63.
  62. Liaquat, A.M., Kalam, M.A., Masjuki, H.H., Jayed, M.H., 2010. Potential emissions reduction in road transport sector using biofuel in developing countries. Atmos Environ. 44(32), 3869-3877.
  63. Lin, W.Y., Chang, Y.Y., Hsieh, Y.R., 2010. Effect of ethanol-gasoline blends on small engine generator energy efficiency and exhaust emission. J. Air Waste Manage. Assoc. 60(2), 142-148.
  64. Liu, X., Wang, H., Zheng, Z., Liu, J., Reitz, R.D., Yao, M., 2016. Development of a combined reduced primary reference fuel-alcohols (methanol/ethanol/propanols/butanols/n-pentanol) mechanism for engine applications. Energy. 114, 542-558.
  65. Liu, Z., Sun, P., Du, Y., Yu, X., Dong, W., Zhou, J., 2021. Improvement of combustion and emission by combined combustion of ethanol premix and gasoline direct injection in SI engine. Fuel. 292, 120403.
  66. Lynd, L.R., Elamder, R.T., Wyman, C.E., 1996. Likely features and costs of mature biomass ethanol technology. Appl. Biochem. Biotechnol. 57, 741-761.
  67. Mahmudul, M., Hagos, F.Y., Mamat, R., Adam, A.A., Ishak, W.F.W., Alenezi R., 2017. Production, characterization and performance of biodiesel as an alternative fuel in diesel engines-a review. Renew. Sust. Energy Rev. 72, 497-509.
  68. Masum, B.M., Masjuki, H.H., Kalam, M.A., Palash S.M., Habibullah. M., 2015. Effect of alcohol-gasoline blends optimization on fuel properties, performance and emissions of a SI engine. J. Clean. Prod. 86, 230-237.
  69. Masum, B.M., Masjuki, H.H., Kalam, M.A., Fattah, I.R., Palash, S.M., Abedin M.J., 2013. Effect of ethanol-gasoline blend on NOx emission in SI engine. Renew. Sust. Energy Rev. 24, 209-222.
  70. Melo, T.C.C., Machado, G.B., Belchior, C.R., Colaço, M.J., Barros, J.E., de Oliveira, E.J., de Oliveira, D.G., Hydrous ethanol-gasoline blends-Combustion and emission investigations on a Flex-Fuel engine. Fuel. 97, 796-804.
  71. Mofijur, M.G.R.M., Rasul, A.M., Hyde, J., Azad, A.K., Mamat, R., Bhuiy, M.M.K., 2016. Role of biofuel and their binary (diesel-biodiesel) and ternary (ethanol-biodiesel-diesel) blends on internal combustion engines emission reduction. Renew. Sust. Energy Rev. 53, 265-278.
  72. Mohammed, M.K., Balla, H.H., Al-Dulaimi, Z.M.H., Kareem, Z.S., Al-Zuhairy, M.S., 2021. Effect of ethanol-gasoline blends on SI engine performance and emissions. Case Stud. Therm. Eng. 25, 100891.
  73. Nadaleti, W.C., Przybyla, G., 2018. Emissions and performance of a spark-ignition gas engine generator operating with hydrogen-rich syngas; methane and biogas blends for application in southern Brazilian rice industries. Energy. 154, 38-51.
  74. Naik, S.N., Goud, V.V., Rout, P.K., Dalai, A.K., 2010. Production of first and second generation biofuels: a comprehensive review. Renew. Sust. Energy Rev. 14(2), 578-597.
  75. Najafi, G., Ghobadian, B., Moosavian, A., Yusaf, T., Mamat, R., Kettner, M., Azmi, W.H., 2016. SVM and ANFIS for prediction of performance and exhaust emissions of a SI engine with gasoline-ethanol blended fuels. Appl. Therm. Eng. 95, 186-203.
  76. Najafi, G., Ghobadian, B., Tavakoli, T., Buttsworth, D.R., Yusaf, T.F., Faizollahnejad, M., 2009. Performance and exhaust emissions of a gasoline engine with ethanol blended gasoline fuels using artificial neural network. Appl. Energy. 86(5), 630-639.
  77. Nocera, S., Cavallaro, F. 2016. The competitiveness of alternative transport fuels for CO2 Transp. Policy. 50, 1-14.
  78. Normann, F., Andersson, K., Leckner, B., Johnsson, F., 2009. Emission control of nitrogen oxides in the oxy-fuel process. Prog. Energy Combust. Sci. 35(5), 385-397.
  79. Oh, H., Bae, C., Min, K., 2010. Spray and combustion characteristics of ethanol blended gasoline in a spray guided DISI engine under lean stratified operation. SAE Int. J. Engines. 3(2), 213-222.
  80. Örs, İ., Sayin, B., Ciniviz, M., 2020. A comparative study of ethanol and methanol addition effects on engine performance, combustion and emissions in the SI engine. Int. J. Automot. Sci. Technol. 4(2), 59-69.
  81. Ozsezen, A.N., Canakci, M., 2011. Performance and combustion characteristics of alcohol-gasoline blends at wide-open throttle. Energy. 36(5), 2747-2752.
  82. Pang, X., Mu, Y., Yuan, J., He, H., 2008. Carbonyls emission from ethanol-blended gasoline and biodiesel-ethanol-diesel used in engines. Atmos. Environ. 42(6), 1349-1358.
  83. Pischinger, S., Günther, M., Budak, O., 2017. Abnormal combustion phenomena with different fuels in a spark ignition engine with direct fuel injection. Combust. Flame. 175, 123-137.
  84. Ramasamy, D., Goh, C.Y., Kadirgama, K., Benedict, F., Noor, M.M., Najafi, G., Carlucci, A.P., 2017. Engine performance, exhaust emission and combustion analysis of a 4-stroke spark ignited engine using dual fuel injection. Fuel. 207, 719-728.
  85. Ramli, N.N., Epplin, F.M., 2017. Cost to produce liquid biofuel from invasive eastern redcedar biomass. Biomass Bioenergy. 104, 45-52.
  86. Roozbehani, B., Mirdrikvand, M., Moqadam, S.I., Roshan, A.C., 2013. Synthetic ethanol production in the Middle East: a way to make environmentally friendly fuels. Chem. Technol. Fuels Oils. 49(2), 115-124.
  87. Rosdi, S.M., Mamat, R., Alias, A., Hamzah, H., Sudhakar, K., Hagos, F.Y., 2020, May. Performance and emission of turbocharger engine using gasoline and ethanol blends. IOP Conf. Ser.: Mater. Sci. Eng. 863(1), 012034. IOP Publishing.
  88. Saravanan, A.P., Mathimani, T., Deviram, G., Rajendran, K., Pugazhendhi, A., 2018. Biofuel policy in India: a review of policy barriers in sustainable marketing of biofuel. J. Clean. Prod. 193, 734-747.
  89. Schifter, I., Diaz, L., Lopez-Salinas, E., 2005. Hazardous air pollutants from mobile sources in the metropolitan area of Mexico City. J. Air Waste Manage. Assoc. 55(9), 1289-1297.
  90. Schifter, I., Diaz, L., Rodriguez, R., Gómez, J.P., Gonzalez, U., 2011. Combustion and emissions behavior for ethanol-gasoline blends in a single cylinder engine. Fuel. 90(12), 3586-3592.
  91. Schifter, I.D.L.G.J.P.G., Diaz, L., Gómez, J.P., Gonzalez, U., 2013. Combustion characterization in a single cylinder engine with mid-level hydrated ethanol-gasoline blended fuels. Fuel. 103, 292-298.
  92. Shahir, S.A., Masjuki, H.H., Kalam, M.A., Imran, A., Ashraful, A.M., 2015. Performance and emission assessment of diesel-biodiesel-ethanol/bioethanol blend as a fuel in diesel engines: a review. Renew. Sust. Energy Rev. 48, 62-78.
  93. Sims, R.E, Taylor, M., Saddler, J., Mabee, W., 2010. An overview of second generation biofuel technologies. Technol. 101(6), 1570-1580.
  94. Singh, E., Shukla, M.K., Pathak, S., Sood, V., Singh., N., 2014. Performance emission & noise characteristics evaluation of n-butanol/gasoline blend in constant speed SI engine. Int. J. Eng. Res. Technol. 3(11), 993-999.
  95. Song, C.L., Zhou, Y.C., Huang, R.J., Wang, Y.Q., Huang, Q.F., Lü, G., Liu, K.M., 2007. Influence of ethanol-diesel blended fuels on diesel exhaust emissions and mutagenic and genotoxic activities of particulate extracts. J. Hazard. Mater. 149(2), 355-363.
  96. Srinivasan, C.A., Saravanan, C.G., 2010. Emission reduction in SI engine using ethanol-gasoline blends on thermal barrier coated pistons. Int. J. Energy Environ. 1(1), 715-726.
  97. Storey, J.M., Barone, T., Norman, K., Lewis, S., 2010. Ethanol blend effects on direct injection spark-ignition gasoline vehicle particulate matter emissions. SAE Int. J. Fuels Lubricants. 3(2), 650-659.
  98. Szulczyk, K.R., McCarl, B.A., Cornforth, G., 2010. Market penetration of ethanol. Renew. Sust. Energy Rev. 14(1), 394-403.
  99. Taghavifar, H., Kaleji, B.K., Kheyrollahi, J., 2020. Application of composite TNA nanoparticle with bio-ethanol blend on gasoline fueled SI engine at different lambda ratios. Fuel. 277, 118218.
  100. Taneja, S., Parmar A., 2019. Analysis of the engine characteristics of a variable compression ratio SI engine fuelled with various gasoline-ethanol blends. AIP Conf. Proc. 2148(1), 030056.
  101. Thakur, A.K., Kaviti, A.K., Mehra R., Mer, K.K.S., 2017a. Performance analysis of ethanol-gasoline blends on a spark ignition engine: a review. 8(1), 91-112.
  102. Thakur, A.K., Kaviti, A.K., Mehra, R., Mer, K.K.S., 2017b. Progress in performance analysis of ethanol-gasoline blends on SI engine. Renew. Sust. Energy Rev. 69, 324-340.
  103. Thangavel, V., Momula, S.Y., Gosala, D.B., Asvathanarayanan, R., 2016. Experimental studies on simultaneous injection of ethanol-gasoline and n-butanol-gasoline in the intake port of a four stroke SI engine. Renewable Energy. 91, 347-360.
  104. Tian, Z., Zhen, X., Wang, Y., Liu, D., Li, X. 2020. Comparative study on combustion and emission characteristics of methanol, ethanol and butanol fuel in TISI engine. Fuel. 259, 116199.
  105. Tibaquirá, J.E., Huertas, J.I., Ospina, S., Quirama, L.F., Niño, J.E., 2018. The effect of using ethanol-gasoline blends on the mechanical, energy and environmental performance of in-use vehicles. Energies. 11(1), 22
  106. Turner, D., Xu, H., Cracknell, R.F., Natarajan, V., Chen X., 2011. Combustion performance of bio-ethanol at various blend ratios in a gasoline direct injection engine. Fuel. 90(5), 1999-2006.
  107. Varatharajan, K., Cheralathan, M., 2012. Influence of fuel properties and composition on NOx emissions from biodiesel powered diesel engines: a review. Renew. Sust. Energy Rev. 16(6), 3702-3710.
  108. Verma, S., Sharma, B., Ahmad, J., Dwivedi, G., Nandan, G., 2018. Impact assessment of ethanol as fuel for engine operation. Mater. Today:. Proc. 5(2), 6115-6120.
  109. Veza, I., Said, M.F.M., Latiff, Z.A., 2020. Improved performance, combustion and emissions of SI engine fuelled with butanol: a review. Int. J. Automot. Mech. Eng. 17(1), 7648-7666.
  110. Wen, L.B., Xin, C.Y., Yang, S.C., 2010. The effect of adding dimethyl carbonate (DMC) and ethanol to unleaded gasoline on exhaust emission. Appl. Energy. 87(1), 115-121.
  111. Yang, H.H., Liu, T.C., Chang, C.F., Lee, E., 2012. Effects of ethanol-blended gasoline on emissions of regulated air pollutants and carbonyls from motorcycles. Appl. Energy. 89(1), 281-286.
  112. Yao, Y.C., Tsai, J.H., Chiang, H.L., 2009. Effects of ethanol-blended gasoline on air pollutant emissions from motorcycle. Sci. Total Environ. 407(19), 5257-5262.
  113. Yao, Y.C., Tsai, J.H., Wang, I.T., 2013. Emissions of gaseous pollutant from motorcycle powered by ethanol-gasoline blend. Appl. Energy. 102, 93-100.
  114. Yoon, S.H., Ha, S.Y., Roh, H.G., Lee, C.S., 2009. Effect of bioethanol as an alternative fuel on the emissions reduction characteristics and combustion stability in a spark ignition engine. Proc. Inst. Mech. Eng., Part D: J. Automob. Eng. 223(7), 941-951.
  115. Yücesu, H.S., Topgül, T., Çinar, C., Okur, M., 2006. Effect of ethanol-gasoline blends on engine performance and exhaust emissions in different compression ratios. Appl. Thermal Eng. 26(17-18), 2272-2278.
  116. Yusoff, M.N.A.M., Zulkifli, N.W.M., Masum, B.M., Masjuki, H.H., 2015. Feasibility of bioethanol and biobutanol as transportation fuel in spark-ignition engine: a review. RSC Adv. 5(121), 100184-100211.
  117. Yusri, M., Mamat, R., Najafi, G., Razman, A., Awad, O.I., Azmi, W.H., Ishak, W.F.W., Shaiful, A.I.M., 2017a. Alcohol based automotive fuels from first four alcohol family in compression and spark ignition engine: a review on engine performance and exhaust emissions. Renew. Sust. Energy Rev. 77, 169-181.
  118. Yusri, I.M., Mamat, R., Azmi, W.H., Omar, A.I., Obed, M.A., Shaiful, A.I.M., 2017b. Application of response surface methodology in optimization of performance and exhaust emissions of secondary butyl alcohol-gasoline blends in SI engine. Energy Convers. Manage. 133, 178-195.
  119. Yusri, I.M., Mamat, R., Azmi, W.H., Najafi, G., Sidik, N.A.C., Awad, O.I., 2016. Experimental investigation of combustion, emissions and thermal balance of secondary butyl alcohol-gasoline blends in a spark ignition engine. Energy Convers. Manage. 123, 1-14.
  120. Zervas, E., Montagne, X., Lahaye, J., 2003. Emissions of regulated pollutants from a spark ignition engine. Influence of fuel and air/fuel equivalence ratio. Environ. Sci. Technol. 37(14), 3232-3238.
  121. Zervas, E., Tazerout, M., 2000. Organic acids emissions from natural-gas-fed engines. Atmos. Environ. 34(23), 3921-3929.
  122. Zhuang, Y., Hong, G., 2013. Primary investigation to leveraging effect of using ethanol fuel on reducing gasoline fuel consumption. Fuel. 105, 425-431.