A comprehensive review on the implementation of the biorefinery concept in biodiesel production plants

Botero Gutiérrez, Christian David; Restrepo Serna, Daissy Lorena; Cardona Alzate, Carlos Ariel

doi:10.18331/BRJ2017.4.3.6

A comprehensive review on the implementation of the biorefinery concept in biodiesel production plants

Document Type : Review Paper

Authors

Christian David Botero Gutiérrez ¹

Daissy Lorena Restrepo Serna ²

Carlos Ariel Cardona Alzate ²

¹ Instituto de Biotecnología y Agroindustria, Departamento de Ingeniería Química, Universidad Nacional de Colombia sede Manizales, Km. 7 vía al Magdalena, Manizales, Colombia.

² Instituto de Biotecnología y Agroindustria, Departamento de Ingeniería Química, Universidad Nacional de Colombia sede Manizales, Km. 7 vía al Magdalena, Manizales, Colombia.

10.18331/BRJ2017.4.3.6

Abstract

Biodiesel is a promising alternative to petroleum diesel and its production from various generations of feedstocks by using different technologies has been constantly growing globally. However, in spite of such large scale of production, serious considerations should be taken into account to ensure the long-term sustainability of biodiesel production. This issue becomes more of concern given the fact that some generations of feedstocks used for biodiesel production are in clear conflict with food security. The concept of biorefinery has been at the center of attention with an aim to address these challenges by promoting an integral use of biomass to allow the production of multiple products along with biodiesel. Such implementation has been extensively studied over the last years and is expected to lead to economic, environmental, and social advantages over individual processes. The current review first presented an overview on biodiesel, its different feedstocks, and production technologies. Subsequently, the biorefinery concept and its correct implementation was technically discussed. Biodiesel production under the biorefinery scheme was also presented. Finally, techno-economic analysis of biodiesel production under the biorefinery concept by considering palm oil-based biorefinery as case study was investigated.

Graphical Abstract

A comprehensive review on the implementation of the biorefinery concept in biodiesel production plants

Highlights

Integral use of biomass under biorefinery concept in general leads to economic, environmental, and social advantages over individual processes.

Biorefineries must be conceptualized beforehand in order to achieve optimal selection of technologies, raw materials, and products.

Sole production of biodiesel on the analyzed scale would not cover all the production costs.

Multiple-products production such as xylitol, ethanol, syngas, and electricity in addition to biodiesel would enhance the overall viability of the plant.

Keywords

Biorefinery

Conceptual design

Biodiesel

Economic viability

Environmental Sustainability

[1] Aguilar, R., Ramırez, J.A., Garrote, G., Vázquez, M., 2002. Kinetic study of the acid hydrolysis of sugar cane bagasse. Int. J. Food Eng. 55(4), 309-318.

[2] Ali, C.H., Qureshi, A.S., Mbadinga, S.M., Liu, J.F., Yang, S.Z., Mu, B.Z., 2017. Biodiesel production from waste cooking oil using onsite produced purified lipase from Pseudomonas aeruginosa FW_SH-1: central composite design approach. Renewable Energy. 109, 93-100.

[3] Aranda-Barradas, J.S., Delia, M.L., Riba, J.P., 2000. Kinetic study and modelling of the xylitol production using Candida parapsilosis in oxygen-limited culture conditions. Bioprocess. Biosyst. Eng. 22(3), 219-225.

[4] Azad, A.K., Rasul, M.G., Khan, M.M.K., Sharma, S.C., Hazrat, M.A., 2015. Prospect of biofuels as an alternative transport fuel in Australia. Rene. Sust. Energy Rev. 43, 331-351.

[5] Bambase, M.E., Nakamura, N., Tanaka, J., Matsumura, M., 2007. Kinetics of hydroxide‐catalyzed methanolysis of crude sunflower oil for the production of fuel‐grade methyl esters. J. Chem. Technol. Biotechnol. 82(3), 273-280.

[6] Barnwal, B.K., Sharma, M.P., 2005. Prospects of biodiesel production from vegetable oils in India. Rene. Sust. Energy Rev. 9(4), 363-378.

[7] Bhattacharyya, S.C., 2011. The economics of renewable energy supply, in: Energy economics: concepts, issues, markets and governance, Springer-Verlag, London, 249–271.

[8] Biodiesel fill stations and prices. http://www.usabiodieselprices.com/station_map.php. (accessed on 17 April 2017).

[9] Canakci, M., Van Gerpen, J., 2001. A pilot plant to produce biodiesel from high free fatty acid feedstocks. Am. Soc. Agric. Eng. 46(4), 945-954.

[10] Cardona, C.A., Aristizábal, V., Solarte, J.C., 2016. Improvement of palm oil production for food industry through biorefinery concept, in: Taylor, J.C. (Ed.), Advances in Chemistry Research. Nova Science Publishers, NY, USA, pp. 1-36.

[11] Chang, S.H., 2014. An overview of empty fruit bunch from oil palm as feedstock for bio-oil production. Biomass Bioenergy. 62, 174-181.

[12] Cherubini, F., 2010. The biorefinery concept: using biomass instead of oil for producing energy and chemicals. Energy Convers. Manage. 51(7), 1412-1421.

[13] Cherubini, F., Ulgiati, S., 2010. Crop residues as raw materials for biorefinery systems - an LCA case study. Appl. Energy. 87(1), 47-57.

[14] Chew, K.W., Yap, J.Y., Show, P.L., Suan, N.H., Juan, J.C., Ling, T.C., Lee, D.J., Chang, J.S., 2017. Microalgae biorefinery: high value products perspectives. Bioresour. Technol. 229, 53-62.

[15] Chisti, Y., 2013. Constraints to commercialization of algal fuels. J. Biotechnol. 167(3), 201-214.

[16] Christenson, D.P., Goldfarb, J.L., Kriner, D.L., 2017. Costs, benefits, and the malleability of public support for “Fracking”. Energy Policy. 105, 407-417.

[17] Dávila, J.A., Hernández, V., Castro, E., Cardona, C.A., 2014. Economic and environmental assessment of syrup production. Colombian case. Bioresour. Technol. 161, 84-90.

[18] Daza, L.V., Solarte, J.C., Serna, S., Chacón, Y., Cardona, C.A., 2016. Agricultural waste management through energy producing biorefineries: The Colombian case. Waste Biomass Valorization. 7(4), 789-798.

[19] Dias, J.M., Alvim-Ferraz, M.C., Almeida, M.F., 2008. Mixtures of vegetable oils and animal fat for biodiesel production: influence on product composition and quality. Energy Fuels. 22(6), 3889-3893.

[20] EPM | Empresa de servicios públicos de Colombia (accessed on 17 April 2017).

[21] Fassinou, W.F., 2012. Higher heating value (HHV) of vegetable oils, fats and biodiesels evaluation based on their pure fatty acids' HHV. Energy. 45(1), 798-805.

[22] Feyzi, M., Hosseini, N., Yaghobi, N., Ezzati, R., 2017. Preparation, characterization, kinetic and thermodynamic studies of MgO-La₂ O₃ nanocatalysts for biodiesel production from sunflower oil. Chem. Phys. Lett. 677, 19-29.

[23] Fisher scientific: lab equipment and supplies (accessed on 17 April 2017).

[24] Ghatak, H.R., 2011. Biorefineries from the perspective of sustainability: feedstocks, products, and processes. Renew. Sust. Energy Rev. 15(8), 4042-4052.

[25] González-Delgado, Á.D., Kafarov, V., 2011. Microalgae based biorefinery: issues to consider. CT&F-Ciencia, Tecnología y Futuro. 4(4), 5-22.

[26] Gutiérrez, L.F., Sánchez, Ó.J., Cardona, C.A., 2009. Process integration possibilities for biodiesel production from palm oil using ethanol obtained from lignocellulosic residues of oil palm industry. Bioresour. Technol. 100(3), 1227-1237.

[27] Helwani, Z., Othman, M.R., Aziz, N., Fernando, W.J.N., Kim, J., 2009. Technologies for production of biodiesel focusing on green catalytic techniques: a review. Fuel Process. Technol. 90(12), 1502-1514.

[28] Huang, G., Chen, F., Wei, D., Zhang, X., Chen, G., 2010. Biodiesel production by microalgal biotechnology. Appl. Energy. 87(1), 38-46.

[29] ICIS. (accessed on 13 April 2017).

[30] IndexMundi Statistics (accessed on 15 April 2017).

[31] Leung, D.Y., Wu, X., Leung, M.K.H., 2010. A review on biodiesel production using catalyzed transesterification. Appl. Energy. 87(4), 1083-1095.

[32] Likozar, B., Levec, J., 2014. Transesterification of canola, palm, peanut, soybean and sunflower oil with methanol, ethanol, isopropanol, butanol and tert-butanol to biodiesel: Modelling of chemical equilibrium, reaction kinetics and mass transfer based on fatty acid composition. Appl. Energy 123:108-120.

[33] Long, N.V.D., Kim, S., Lee, M., 2016. Design and optimization of intensified biorefinery process for furfural production through a systematic procedure. Biochem. Eng. J. 116, 166-175.

[34] Lü, J., Sheahan, C., Fu, P., 2011. Metabolic engineering of algae for fourth generation biofuels production. Energy Environ. Sci. 4(7), 2451-2466.

[35] Manatura, K., Lu, J.H., Wu, K.T., Hsu, H.T., 2017. Exergy analysis on torrefied rice husk pellet in fluidized bed gasification. Appl. Therm. Eng. 111, 1016-1024.

[36] Mansoornejad, B., Chambost, V., Stuart, P., 2010. Integrating product portfolio design and supply chain design for the forest biorefinery. Chem. Phys. Lett. 34(9), 1497-1506.

[37] Marchetti, J.M., Miguel, V.U., Errazu, A.F., 2007. Possible methods for biodiesel production. Renew. Sust. Energy Rev. 11(6), 1300-1311.

[38] Martinez-Hernandez, E., Sadhukhan, J., Campbell, G.M., 2013. Integration of bioethanol as an in-process material in biorefineries using mass pinch analysis. Appl. Energy. 104, 517-526.

[39] Mata, T.M., Martins, A.A., Caetano, N.S., 2010. Microalgae for biodiesel production and other applications: A review. Renew. Sust. Energy Rev. 14(1), 217-232.

[40] Math, M.C., Kumar, S.P., Chetty, S.V., 2010. Technologies for biodiesel production from used cooking oil - A review. Energy Sustainable Dev. 14(4), 339-345.

[41] Mathioudakis, V., Gerbens-Leenes, P.W., Van der Meer, T.H., Hoekstra, A.Y., 2017. The water footprint of second-generation bioenergy: A comparison of biomass feedstocks and conversion techniques. J. Cleaner Prod. 148, 571-582.

[42] Meher, L.C., Sagar, D.V., Naik, S.N., 2006. Technical aspects of biodiesel production by transesterification - a review. Renew. Sust. Energy Rev. 10(3), 248-268.

[43] Moncada, J., Aristizábal, V., Cardona, C.A., 2016. Design strategies for sustainable biorefineries. Biochem. Eng. J. 116, 122-134.

[44] Moncada, J., El-Halwagi, M.M., Cardona, C.A., 2013. Techno-economic analysis for a sugarcane biorefinery: Colombian case. Bioresour. Technol. 135, 533-543.

[45] Moncada, J., Hernández, V., Chacón, Y., Betancourt, R., Cardona, C. A., 2015. Citrus based biorefineries. in: Simmons, D., (Eds.) Citrus fruits. production, consumption and health benefits, Nova Publishers, pp. 1–26.

[46] Moncada, J., Tamayo, J.A., Cardona, C.A., 2014. Integrating first, second, and third generation biorefineries: Incorporating microalgae into the sugarcane biorefinery. Chem. Eng. Sci. 118, 126-140.

[47] Mosquera, M., Valderrama, M., Fontanilla, C., Ruíz, E., Uñate, M., Rincón, F., Arias, N. 2016. Costos de producción de la agroindustria de la palma de aceite en Colombia en 2014. Palmas. 37(2), 37-53.

[48] Montoya, M.R., Cardona, C.A., Orrego, C., Gutiérrez, L., 2006. Obtención de biodiesel por reacción extractiva. Rev. Energía y Comput. 14(2), 49–57.

[49] Mussatto, S.I., Santos, J.C., Filho, W.C., Silva, S.S., 2005. Purification of xylitol from fermented hemicellulosic hydrolyzate using liquid–liquid extraction and precipitation techniques. Biotechnol. Lett. 27(15), 1113-1115.

[50] Naik, S.N., Goud, V.V., Rout, P.K., Dalai, A.K., 2010. Production of first and second generation biofuels: a comprehensive review. Renew. Sust. Energy Rev. 14(2), 578-597.

[51] Nasdaq. globenewswire. hongli clean energy technologies corp. reports fiscal year 2016 q2 financial results Nasdaq: CETC. https://globenewswire.com/ (accessed on 17 April 2017).

[52] Negm, N.A., Sayed, G.H., Yehia, F.Z., Habib, O.I., Mohamed, E.A., 2017. Biodiesel production from one-step heterogeneous catalyzed process of Castor oil and Jatropha oil using novel sulphonated phenyl silane montmorillonite catalyst. J. Mol. Liq. 234, 157-163.

[53] O’Keeffe, S., Schulte, R.P.O., Sanders, J.P.M., Struik, P.C., 2012. II. Economic assessment for first generation green biorefinery (GBR): scenarios for an Irish GBR blueprint. Biomass Bioenergy. 41, 1-13.

[54] Patel, R.L., Sankhavara, C.D., 2017. Biodiesel production from Karanja oil and its use in diesel engine: a review. Renew. Sust. Energy Rev. 71, 464-474.

[55] Philippidis, G.P., Smith, T.K., Wyman, C.E., 1993. Study of the enzymatic hydrolysis of cellulose for production of fuel ethanol by the simultaneous saccharification and fermentation process. Biotechnol. Bioeng. 41(9), 846-853.

[56] Pitt, W.W., Haag, G.L., Lee, D.D., 1983. Recovery of ethanol from fermentation broths using selective sorption-desorption. Biotechnol. Bioeng. 25(1), 123-131.

[57] Posada, J.A., Rincón, L.E., Cardona, C.A., 2012. Design and analysis of biorefineries based on raw glycerol: addressing the glycerol problem. Bioresour. Technol. 111, 282-293.

[58] Prasertsan, S., Prasertsan, P., 1996. Biomass residues from palm oil mills in Thailand: an overview on quantity and potential usage. Biomass Bioenergy. 11(5), 387-395.

[59] Proyección de demanda combustibles líquidos en Colombia, Unidad Planeación Min. Energética, UPME, 2016.

[60] Quintero, J.A., Felix, E.R., Rincón, L.E., Crisspín, M., Baca, J.F., Khwaja, Y., Cardona, C.A., 2012. Social and techno-economical analysis of biodiesel production in Peru. Energy Policy. 43, 427-435.

[61] Rincón, L.E., Jaramillo, J.J., Cardona, C.A., 2014. Comparison of feedstocks and technologies for biodiesel production: An environmental and techno-economic evaluation. Renewable Energy. 69, 479-487.

[62] Rincón, L.E., Moncada, J., Cardona, C.A., 2014. Analysis of potential technological schemes for the development of oil palm industry in Colombia: a biorefinery point of view. Ind. Crops Prod. 52, 457-465.

[63] Rivera, E.C., Costa, A.C., Atala, D.I., Maugeri, F., Maciel, M.R.W., Filho, R.M., 2006. Evaluation of optimization techniques for parameter estimation: application to ethanol fermentation considering the effect of temperature. Process Biochem. 41(7), 1682-1687.